Expansion alloys leverage their ability to significantly expand in volume when heated, effectively securing and sealing structural connections.
With continuous advances in industrial technology, expansion alloys are steadily emerging as standout products in the field of engineering materials, thanks to their superior physical properties and performance benefits. This article will begin by exploring the basic principles of expansion alloys, followed by a detailed analysis of the commonly used international grades and their corresponding standards, helping engineers and industry professionals quickly grasp the key points for material selection and application.
Expansion alloys are mainly used in Sealing and Fastening of Structural Connections, Low Thermal Expansion Applications, Glass-Sealing in Electronic Devices.
| TYPE | ALLOY No. | Main Chemical Components | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| China | Russia | France Imphy |
Germany VAC |
UK Telcan |
USA Magnetics Carpenter |
Japan Sumitomo |
ASTM UNS No. |
ASTM Spec No. | ||
| Glass Sealing and controlled expansion Alloys | 4J28 | 28X | LTM(FR) | FR‑25(GER) VaCovito25(GER) |
Croloy27(UK) 26Cr-Fe(UK) |
FR‑28 Carpenter 27 Glass Sealing “27” Alloy 27 |
Cr28(JPN) | K92801 | F256 | FeCr28 |
| 4J29 | 29НК 29НК-ВИ |
Dilver P0 Dilver P1 |
Vacon 12 Silvar 48(GER) |
Nilo K (UK) Teleaseal |
Kovar Rodar Techallony Glasseal29-17 |
KV-1(JPN) KV-2(JPN) KV-3(JPN) |
K94610 | F15 | FeNi29Co17 | |
| Glass Sealing and Metal-to-Ceramic Sealing Alloys | 4J42 | 42Н | Dumet42 N42(FR) |
Vacodil 42 Nilo42(GER) |
Nilo 42(UK) | Glass sealing 42 Uniseal 42 42 Alloy |
D(JPN) YEF42(JPN) NSD(JPN) |
K94100 | F30 | FeNi42 |
| 4J45 | 46Н | Fe-Ni42(FR) N48(FR) |
Vacodil 46 | Nilo45 | CarPerterG Niromet 46 Ferrovac 46 Ni 46 Alloy |
K94600 | F30 | FeNi45 FeNi46 |
||
| 4J50 | 50Н | N50(FR) | Vacovit 500(GER) | Nilo51(UK) | 52 Alloy FeNi50 |
NS-1(JPN) | N14052 | F30 | FeNi50 | |
| 4J49 | 49НХР | FeNi46Cr5 | Vacovit 465 Vacovit 485 |
Carpenter 456 | K95150 | F31 | FeNi47Cr6 | |||
| 4J6(4J06) | Н42 X 6 | ASV(426) Ni42Cr6 |
Vacovit 426 NiCr426 |
Nilo 45(UK) | 42Ni-6Cr Carpenter426 Sylvania4 Sealmet 4 |
NRS-1(JPN) YEF-426(JPN) SNC(JPN) |
K94760 | F31 | FeNi42Cr6 | |
| Metal-to-Ceramic Sealing Alloys | 4J33 | 33Hk(Ni33Co17) | KV-4(Ni33Co17) | K94630 | F1466 | FeNi33Co15 FeNi29Co17 |
||||
| 4J34 | 31HK(Ni31Co20) | Vacon20(Ni28Co20) | Ceramvar(Ni27Co25) | K94620 | F1466 | FeNi27Co25 | ||||
| Low Thermal Expansion Alloys | 4J32 | 32НКД 32НК-ВИ |
Invar(FR) Surperieur (FR) |
Super-Invar32-5 Super Nilvar |
SI (JPN) | K93500 | F1684 | FeNi32Co4Cu | ||
| 4J36 | 36Н 36Н-ВИ |
Invar Standard Fe-Ni36 |
Vacodil 36 Nilos36(GER) |
Invar (UK) Nilo 36 (UK) 36Ni(UK) |
Invar 36 Nilvar Unipsan36 |
PD(JPN) Cactus LE(JPN) |
K93600 / K93603 / K93050 | F1684 | FeNi36 | |
The production of expansion alloys begins with precise blending of metallic and non-metallic raw materials, followed by high-temperature smelting (vacuum or non-vacuum) to eliminate impurities and form a homogeneous melt. The molten metal is then shaped into base billets via hot rolling processes such as forging or rolling. Cold rolling and finishing further enhance surface smoothness and dimensional accuracy. Heat treatment, including annealing or aging, refines the microstructure and mechanical properties to achieve the required thermal expansion coefficients. Precision machining techniques like cutting and polishing transform the billets into specific components, which undergo rigorous quality testing to validate expansion behavior, strength, and corrosion resistance. Finally, graded products are packaged for applications in high-precision electronics, aerospace systems, and energy infrastructure, where their exceptional thermal stability drives innovation in cutting-edge technologies.
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